In the Taurus Mountains Simon stays with descendants of the original Turks, nomads known as Yoruks, whose lifestyle is under threat from the modern world and an increasingly religious government. They're not the only minority at odds with the authorities in Turkey; Simon sees first-hand the devastating effects of fighting in the country's Kurdish region. In an area where the government has detained foreign journalists, Simon gathers unique footage in the aftermath of a crackdown on Kurdish militants - the wholesale destruction of the historic centre of one of Turkey's oldest cities.
Away from the conflict in the south, Simon heads towards the Black Sea coast. He meets a wildlife conservationist protecting Turkey's population of brown bears, and villagers who still communicate over long distances using an ancient bird language. In the country's capital he meets a victim of President Erdogan's authoritarian purge of people accused of complicity in the failed coup against him.
Finally Simon's journey comes full circle when he returns to Istanbul - home to the new craze of 'Ottomania', a celebration of the vast empire that preceded modern Turkey. Simon visits the set of one of the world's most popular TV dramas - even getting a speaking role - based in the court of an Ottoman sultan

The fourth episode starts off with the two riding through Santa Cruz, Argentina. The plan is to cross over into Chile and then going up into the Andes. Ewan and Charley head through Argentina’s red rock landscape while a member of their team copes with altitude sickness. The duo are well and truly underway and the first signs of all are well is how well the Harleys hold up in challenging conditions. The roads alternate between unforgiving and pleasant and these e-bikes push through effortlessly. As they ride through Chilean Andes, the audience is shown a picturesque view of the beauty of the countryside, an experience which Boorman calls 'magical.'

Ewan, Charley, and the team land in Ushuaia, the southernmost tip of South America, but tensions arise due to snow and mechanical issues. Traveling 13000 miles over 100 days on electric bikes is hard to imagine. Ewan McGregor and Charles Boorman find out how challenging their mission is as they embark on a journey on prototype Harley Davidsons and the Rivian trucks. The first obstacle is electricity. While parts of the city have no problems with charging the bikes and the trucks, the countryside is where the duo face issues.