Lucy Worsley continues her journey through Russia in the footsteps of the Romanovs, the most powerful royal dynasty in modern European history. In this episode she examines the extraordinary reign of Catherine the Great, and the traumatic conflict with napoleonic France that provides the setting for the novel War and Peace. At the magnificent palace of Peterhof near St Petersburg, Lucy charts the meteoric rise of Catherine the Great, who seized the Russian throne from her husband Peter III in 1762 and became the most powerful woman in the world. Catherine was a woman of huge passions - for art, for her adopted country (she was German by birth) and for her many lovers.
Catherine expanded her empire through military victories overseas, while at home she encouraged education and introduced smallpox inoculation to Russia. But Catherine struggled to introduce deeper reforms, and the institution of serfdom remained largely unchanged. Lucy explains how this injustice fuelled a violent rebellion. Nevertheless, Catherine left Russia more powerful on the world stage than ever. But all she had achieved looked set to be undone when Napoleon invaded Russia in 1812. Lucy relives the pivotal battle of Borodino, when the Russian army finally confronted the French forces; the traumatic destruction of Moscow; and, under Catherine's grandson Alexander, the eventual victory over the French that provided the Romanov dynasty with its most glorious hour.

Hector Berrellez identifies the mysterious Cuban who interrogated Kiki Camarena: a veteran CIA operative, Felix Rodriguez, a key figure in the Iran-Contra scandal. Although warned not to take his investigation further, Hector refuses and is eventually forced into retirement. The case languishes for years, and then a new source comes forward with a shocking allegation.

A team of intrepid palaeontologists recently discovered a lost world of dinosaurs in the unlikeliest of places — deep in the dark, snowy wilds of northern Alaska. Surprisingly, new findings indicates that dinosaurs thrived year-round and raised their young in frigid and dark conditions in the far north of the Arctic Circle.
Rappelling down giant ice cliffs bordering the Colville River, the team wields chainsaws to extract fossils frozen into the permafrost. Newly found dinosaur tracks indicates that a wide variety of species once flourished there, including herds of duck-bills, horned herbivores, pterosaurs, a new type of velociraptor, and northern relatives of T-rex.

Travel from the inner solar system to the Kuiper Belt and explore the moons surrounding the planets of the solar system. Many of these moons that were once unknown are now on the cutting edge of astronomical study. Some burst with volcanic fury another spews icy geysers and others offer the possibility of alien life. Are these strange worlds simply hostile environments unfit for humans or do other possibilities exist? Cutting-edge computer graphics are used to bring the universe down to earth and to imagine what kind of life forms might evolve in alien atmospheres.

Our universe reveals itself in ways we’ve never seen before, thanks to new discoveries in astrobiology. Today, the advent of cutting-edge observational instruments is shedding light on amazing facts about life and the universe. NASA's next-generation space telescope TESS (Exoplanet Survey Satellite) has begun its search for Earth-like planets belonging to other star systems. How many of these 'exoplanets' can host life, and what kind of life forms can evolve in these environments?

American exchange student Amanda Knox is convicted and eventually acquitted for the 2007 death of another student in Italy. Was she a cold-blooded psychopath who brutally murdered her roommate or a naive student abroad trapped in an endless nightmare? Directors Rod Blackhurst (Tribeca Audience Award-winner Here Alone) and Brian McGinn (IDA Award-winner Chef's Table) and producer Mette Heide (Peabody Award-winner India's Daughter) explore the notorious case that made headlines around the world.