Professor Jim Al Khalili from the University of Surrey delves into over 50 years of the BBC science archive to tell the story behind the emergence of one of the greatest theories of modern science, the Big Bang. The remarkable idea that our universe simply began from nothing has not always been accepted with the conviction it is today and, from fiercely disputed leftfield beginnings, took the best part of the 20th century to emerge as the triumphant explanation of how the universe began. Using curious horn-shaped antennas, U-2 spy planes, satellites and particle accelerators, scientists have slowly pieced together the cosmological jigsaw, and this documentary charts the overwhelming evidence for a universe created by a Big Bang.

Guernica (1937) was created during Picasso's Surrealist period and captures the horror of the bombing of the Basque town of Guernica during the Spanish Civil War. By the end of World War II, Picasso had become an internationally known artist and celebrity.

Just under 200 years ago scientists discovered something profound, that electricity is connected to another of nature's most fundamental forces - magnetism. In the second episode, Jim discovers how harnessing the link between magnetism and electricity would completely transform the world, allowing us to generate a seemingly limitless amount of electric power which we could utilise to drive machines, communicate across continents and light our homes. This is the story of how scientists and engineers unlocked the nature of electricity in an extraordinary century of innovation and invention.

The documentary deals with the future of conservation. It begins by looking at previous efforts. The 'Save The Whales' campaign, which started in the 1960s, is seen to have had a limited effect, as whaling continues and fish stocks also decline. In the 1990s, as head of the Kenya Wildlife Service, Richard Leakey took on the poachers by employing armed units. Although it was successful in saving elephants, the policy was detrimental to the Maasai people, who were forced from their land. The need for "fortress" areas is questioned, and the recently highlighted Raja Ampat coral reef in Indonesia is an example. The more tourism it generates, the greater the potential for damage — and inevitable coastal construction. Sustainable development is viewed as controversial, and one contributor perceives it to currently be a "contradiction in terms". Trophy hunting is also contentious. Those that support it argue that it generates wealth for local economies, while its opponents point to the reducing numbers of species such as the markhor. Ecotourism is shown to be beneficial, as it is in the interests of its providers to protect their environments. However, in some areas, such as the Borneo rainforests, the great diversity of species is being replaced by monocultures. The role of both religion and the media in conservation is argued to be extremely important. Contributors to the programme admit a degree of worry about the future, but also optimism.

Andrew Graham-Dixon explores how Russia changed from a feudal nation of aristocratic excess to a hotbed of revolution at the beginning of the 20th century and how art moved from being a servant of the state to an agent of its destruction. From monuments that celebrate the absolutism of the tsars to the epic Russian landscape as inspiration; from the design and construction of gold and glittering palaces to the minutiae of diamond-encrusted Faberge eggs; and eventually to the stark and radical paintings of the avant-garde, the journey through Russian art history is one of extraordinary beauty and surprise.

Audrey Hepburn was a film and fashion icon of the twentieth century and one of the most beloved actresses of all time. She enchanted the world with elegance and innocent charm, and portrayed some of the most memorable characters in film. Although she was one of the few actresses to win an Emmy, Tony, Grammy, and Academy Award, Audrey was modest about her talents, often claiming she had no acting technique. She redefined glamour with elfin features and a waif-like figure that inspired timeless designs by Hubert de Givenchy.Raised in the Netherlands during World War II, Audrey never forgot her own struggles during the German occupation and dedicated her later years to helping needy children around the world, becoming an International Goodwill Ambassador for UNICEF and traveling around the world to provide aid. Audrey Hepburn is remembered as a natural talent, a timeless beauty and a great humanitarian.