After the murder of his brother Frank, Al Capone is out for revenge against William Dever and the Chicago police. He plots to kill every undercover cop that was in Cicero on the day of Frank’s death. Before he can set his plan in motion, however, Johnny Torrio returns from Italy and reclaims his control of their criminal empire. Torrio forbids Capone from killing cops, fearing it would spark an all-out war. Despite Capone’s personal loss, Torrio returns to a booming business that’s raking in $10 million a month. However, as Torrio and Capone’s empire grows, it becomes harder to keep smaller factions under control. After a small group of Italian mobsters attacks one of Dean O’Banion’s distilleries, O’Banion blames Torrio and decides to end their business partnership. He announces his retirement to Torrio and offers Torrio an opportunity to buy him out. Torrio meets O’Banion at the Seine Brewery on May 19, 1924, with the buyout money. Chicago police raid the brewery and arrest Torrio while letting O’Banion walk free: O’Banion had set the whole thing up. With prior convictions, Torrio serves a mandatory prison sentence but is first released on bail. He vows to kill O’Banion as payback and gives Capone his blessing to kill O’Banion. Capone spends months planning the hit. Capone knows that catching O’Banion off guard is nearly impossible, so he places an order with O’Banion’s flower shop for nearly $20,000 worth of flowers, knowing that O’Banion personally oversees his biggest arrangements. On November 10, 1924, O’Banion works in his shop preparing the flower delivery. Two of Capone’s men enter the shop and fatally gun O’Banion down. Four days later, Chicago’s most powerful Irish gangster is laid to rest in one of the most lavish funerals Chicago has ever seen. More than two dozen cars are required to transport floral arrangements as a crowd of 10,000 mourns the death of the infamous gangster. Torrio and Capone attend the funeral, infuriating O’Banion’s top lieutenants, Hymie Weiss and Bugs Moran. Chaos breaks out as smaller gangs through the city begin a turf war. It’s the beginning of an era of bloodshed in Chicago known as the Beer Wars. Over 300 people are murdered at a rate of 75 to 100 murders a year.

Brian considers what it is about our world that makes it a home for life and asks what ingredients were necessary to transform this once barren planet into the Earth we know today? He reveals that it was a rare chain of events combined with the power of life itself that have made Earth unique amongst the cosmos.

In 1927, Prohibition agent Eliot Ness narrowly escapes a hit ordered by Al Capone. Determined to prove to Capone that he's not intimidated, Ness and his team of Untouchables execute a series of high-profile raids on Capone's breweries. Over the course of a few months, they destroy more than 200,000 gallons of beer, worth a modern-day equivalent of $134 million - and the newspapers cover it all. Capone lashes out against Ness in the press. What Capone doesn't realize is that Ness and the Prohibition agents aren't the only ones trying to take him down. For the past four years, another government agency with more manpower and resources than Ness has been going after the infamous kingpin: the Internal Revenue Service.

Dr Alice Roberts looks at our ancestors' seemingly impossible journey to Australia. Miraculously preserved footprints and very old human fossils buried in the outback suggest a mystery: that humans reached Australia almost before anywhere else. How could they have travelled so far from Africa, crossing the open sea on the way, and do it thousands of years before they made it to Europe? The evidence trail is faint and difficult to pick up, but Alice takes on the challenge. In India, new discoveries among the debris of a super volcano hint that our species started the journey much earlier than previously thought, while in Malaysia, genetics points to an ancient trail still detectable in the DNA of tribes today. Alice travels deep into the Asian rainforests in search of the first cavemen of Borneo and tests out a Stone Age raft to see whether sea travel would have been possible thousands of years ago, before coming to a powerful conclusion.

The contests between predators and prey are the most dramatic events in nature. Taking an intimate and detailed look at the remarkable strategies employed by hunters to catch their prey and the hunted to escape. Sir David Attenborough narrates. "The Hardest Challenge" reveals the extraordinary range of techniques predators use to catch their prey - from a leopard using all its powers of stealth to stalk impala in broad daylight to wild dogs, whose tactic is to wear down their prey over long distances; from Nile crocodiles, the planet's most patient predators, to killer whales who use teamwork and intelligence to take on humpback whales. But even with these finely tuned strategies, the outcome is far from certain. Surprisingly, most predators fail most of the time.

Playing with Nuclear Fire' - In March 2011, the Tohoku earthquake in Japan created a tsunami that killed some 16,000 people and crippled the Fukushima Daiichi nuclear power plant. In the aftermath, the government and TEPCO, the plant's operator, withheld information about the extent of the damage. Three years later, citizens and the international community are left wondering if Japan really does have the situation under control, as the government is insisting, or if the danger is far greater than anyone is willing to admit. 'No Man Left Behind' - It's estimated that over a quarter million vets from recent wars have sought treatment for PTSD. Despite these statistics, veterans often face an uphill battle to get treatment, receiving inadequate attention and, most dangerously, overprescribed narcotics and other pharmaceuticals. Ryan Duffy meets veterans struggling with mental illness and addiction.