As the journey continues, there's beauty and danger in equal measure. Charley and Ewan travel through the extraordinary Bolivian desert, but the sandy roads make all more difficult. The duo ride their electric bikes through the exotic and breathtaking countryside and all the way making a challenging ascent. The riders stay in a hotel made entirely out of salt before heading to La Paz. 'Bolivia' also shows some quality work done by UNICEF when it comes to educating and working with the children. McGregor and Boorman spend time with the kids before resuming their journey and ending with a ferry ride over lake Titicaca.

As the journey continues, there's beauty and danger in equal measure for Charley Boorman and Ewan McGrego. The duo ride their electric Harleys through the exotic and breathtaking Bolivian countryside in a tough ascent. The sixth episode showcases some of the challenges the hosts and the crew face when they scale the terrain. One of the Rivians runs into trouble while sandy roads and a heavy breeze sees Boorman take a tumble. Apart from all the accidents, the chapter also shows some quality work done by UNICEF when it comes to educating and working with the children in Bolivia.
The altitude sickness hits Taylor, their logistics man real bad and McGregor starts feeling it as well. The episode ends with a doctor heading to his hotel room to check up on him.

The fourth episode starts off with the two riding through Santa Cruz, Argentina. The plan is to cross over into Chile and then going up into the Andes. Ewan and Charley head through Argentina’s red rock landscape while a member of their team copes with altitude sickness. The duo are well and truly underway and the first signs of all are well is how well the Harleys hold up in challenging conditions. The roads alternate between unforgiving and pleasant and these e-bikes push through effortlessly. As they ride through Chilean Andes, the audience is shown a picturesque view of the beauty of the countryside, an experience which Boorman calls 'magical.'

Ewan, Charley, and the team land in Ushuaia, the southernmost tip of South America, but tensions arise due to snow and mechanical issues. Traveling 13000 miles over 100 days on electric bikes is hard to imagine. Ewan McGregor and Charles Boorman find out how challenging their mission is as they embark on a journey on prototype Harley Davidsons and the Rivian trucks. The first obstacle is electricity. While parts of the city have no problems with charging the bikes and the trucks, the countryside is where the duo face issues.

The band heads to Nashville, Tenn. Dave sits down with Dolly Parton, Tony Joe White, Steve Earle, Willie Nelson, Emmylou Harris and producer Tony Brown to discuss Nashville's musical influences and the Nashville sound. Foo Fighters prepare to record at Southern Ground studio, owned by country musician Zac Brown, who also guests on the song 'Congregation'.

Far from land, where few of us ever venture, is the ocean beyond the boundary of any country. Largely ungoverned, wild, and lawless. Venture into the deep, dark and desolate oceans that are home to an abundance of beautiful - and downright strange - creatures.