The episode opens with Ewan McGregor and Charley Boorman riding through the sleek streets of Guanacaste, Costa Rica. To add to the excitement, the show also introduces us to Ewan's daughter, Jamyan, and the father-daughter duo are lovable to watch. The audience also gets a chance to see the Masaya volcano up close. The red lava is breathtaking and scary at the same time.

New York City, September 11, 2001. The morning everything changed.102 minutes passed between the first plane's impact into One World Trade Center, the second plane's attack on Two World Trade Center, and the eventual collapse of both buildings. In that time, people around New York experienced a range of emotions. Despite the horror and the incomprehensibility of what was happening, many knew, somehow, that they had a unique responsibility to record what they saw. They reached for their cameras.
This unprecedented documentary special joins hundreds of pieces of their footage and audiotape into a single, seamless historical record. It is an intensely personal perspective of the tragedy, communicating for the first time that morning s events, as they were experienced by people around New York. It is an evocative, authentic and reverential memorial to one of the most cataclysmic events in world history.

For Charley Boorman and Ewan McGregor, their journey in the smooth Ecuadorian roads would most definitely have come as a relief after some rough terrain riding. Next up, they stop by one of the factories that make the famed Panama hats. One of the local producers explains that making them by hand takes roughly up to a month. At the other end, the crew on the Rivians make a dash for Central America where they have to ferry their trucks across as the Darién Gap blocks their path. On their way, they make a quick pitstop at one of the cacao factories to know more about cocoa production, one of the economic drivers of the country.

As the journey continues, there's beauty and danger in equal measure. Charley and Ewan travel through the extraordinary Bolivian desert, but the sandy roads make all more difficult. The duo ride their electric bikes through the exotic and breathtaking countryside and all the way making a challenging ascent. The riders stay in a hotel made entirely out of salt before heading to La Paz. 'Bolivia' also shows some quality work done by UNICEF when it comes to educating and working with the children. McGregor and Boorman spend time with the kids before resuming their journey and ending with a ferry ride over lake Titicaca.

Olivia meets someone who seems to truly get her. Andrew has found out about a speed dating event being held in town. He works on his jokes and James Bond impersonations before going to the dinner. Jimmy and Sharnae go on a special holiday together where Jimmy plans a romantic surprise.

Mark has never had a girlfriend, but he wants love more than anything. Maddi and Mark are going on their second date at the Australian Museum. Olivia has had 'a bazillion' unrequited loves but is not ready to give up. Maddi dates a new man who impresses her with his musical talent.