Dr Michael Scott journeys to Athens to discover that from the very start the theatre was about more than just entertainment - it was a reaction to real events, it was a driving force in history and it was deeply connected to Athenian democracy. In fact, the story of theatre is the story of Athens.

In this episode, Helen seeks out the colours that turned planet Earth multicoloured. To investigate the essence of sunlight Helen travels to California to visit the largest solar telescope in the world. She discovers how the most vivid blue is formed from sulfur atoms deep within the Earth's crust and why the presence of red ochre is a key sign of life. In gold, she discovers why this most precious of metals shouldn't even exist on the surface of the planet and in white, Helen travels to one of the hottest places on Earth to explore the role salt and water played in shaping planet Earth.

Andrew Graham-Dixon continues his exploration of German art by looking at the tumultuous 19th and early 20th centuries, and how artists were at the forefront of Germany's drive to become a single nation. Andrew travels to the north and the coastal town of Griefswald, the birthplace of Caspar David Friedrich, the most influential of the German Romantics, to discover how the Baltic coast impacted his mysterious paintings of the German landscape. He also visits Berlin and explores the art of the powerful Prussian state, which would spearhead the unification of Germany in 1871. The episode ends with the outbreak of World War I and the attempts of the artists Franz Marc and Otto Dix to rationalise the catastrophic experiences of the world's first technological war, a war driven by the Prussian innovations.

Graham-Dixon journeys to the country’s scorched centre to explore Spanish art of the 16th and 17th centuries. From the mystical world of El Greco to the tender genius of Velazquez, this was a moment so extraordinary it became known as the Golden Age. But beneath the glittering surface was a dark and savage heart. Travelling from the architectural jewel of Toledo to majestic Madrid, Andrew Graham-Dixon traces the rise and fall of the Spanish Empire, the brutal conquest of the New World, and the religious madness of the Inquisition, to discover how a history so violent could produce some of the most beautiful art ever seen.

This episode explores the nature of the greenhouse effect (discovered by Joseph Fourier and Svante Arrhenius), and the evidence demonstrating the existence of global warming from humanity's influence. Tyson begins by describing the long-term history of the planet Venus; based on readings from the Venera series of probes to the planet, the planet had once had an ocean and an atmosphere, but due to the release of carbon dioxide from volcanic eruptions, the runaway greenhouse effect on Venus caused the surface temperatures to increase and boiled away the oceans. Tyson then notes the delicate nature of the amount of carbon dioxide in the atmosphere can influence Earth's climate due to the greenhouse effect, and that levels of carbon dioxide have been increasing since the start of the 20th century. Evidence has shown this to be from mankind's consumption of oil, coal, and gas instead of from volcanic eruptions due to the isotopic signature of the carbon dioxide. The increase in carbon dioxide has led to an increase in temperatures, in turn leading to positive feedback loops of the melting polar ice caps and dethawing of the permafrost to increase carbon dioxide levels. Tyson then notes that humans have discovered means of harvesting solar power, such as Augustin Mouchot's solar-driven motor in the 19th century, and Frank Shuman's solar-based steam generator in the 1910's. Tyson points out that in both cases, the economics and ease of using cheap coal and oil caused these inventions to be overlooked at the time. Today, solar and wind-power systems would be able to collect enough solar energy from the sun easily. Tyson then compares the motivation for switching to these cleaner forms of energy to the efforts of the Space race and emphasizes that it is not too late for humanity to correct its course.

In episode two, we discover the golden age of the La Tene Celtic warrior and reveal how their world extended as far as central Turkey. But by the middle of the first century BC, the Celts were under threat from an expanding Roman Empire, and the Gallic warrior Vercingetorix would challenge Julius Caesar in an epic battle that would shape the future of Europe.