Lucy Worsley continues her journey through Russia in the footsteps of the Romanovs, the most powerful royal dynasty in modern European history. In this episode she examines the extraordinary reign of Catherine the Great, and the traumatic conflict with napoleonic France that provides the setting for the novel War and Peace. At the magnificent palace of Peterhof near St Petersburg, Lucy charts the meteoric rise of Catherine the Great, who seized the Russian throne from her husband Peter III in 1762 and became the most powerful woman in the world. Catherine was a woman of huge passions - for art, for her adopted country (she was German by birth) and for her many lovers.
Catherine expanded her empire through military victories overseas, while at home she encouraged education and introduced smallpox inoculation to Russia. But Catherine struggled to introduce deeper reforms, and the institution of serfdom remained largely unchanged. Lucy explains how this injustice fuelled a violent rebellion. Nevertheless, Catherine left Russia more powerful on the world stage than ever. But all she had achieved looked set to be undone when Napoleon invaded Russia in 1812. Lucy relives the pivotal battle of Borodino, when the Russian army finally confronted the French forces; the traumatic destruction of Moscow; and, under Catherine's grandson Alexander, the eventual victory over the French that provided the Romanov dynasty with its most glorious hour.

A band that has spanned 40 years pioneering everything from underground rock to the stadium extravaganza, a band that has survived tragedy and shunned celebrity and wrestled publicly with both it's success and it's audience. There have been five members of the band three of which have lead the band in different decades and that's why the question still remains, which one is pink? This film examines the band and it's history in order to discover how they became so successful.

Dr Adam Rutherford shows how decoding the genome has led us to begin to understand the very process by which our DNA makes us different; how it makes each one of us on earth unique and influences who we are and the traits we have. He reveals how, as we try and understand the relationship between who we are and our genes, we stand at the beginning of the most exciting scientific journey of all time.

Episode three explores the mind of one of the most fanatical of all Nazis and the insight that gives into the psychology of dictatorship. Hess is brought to Nuremberg from the UK where he had flown 4 years earlier much to the bemusement of the British. Overy explains that they must have quickly realised he was not normal. In the intervening time Hess’s mental state has further deteriorated and when interviewed by Chief Interrogator Colonel John Amen proclaims amnesia. Chief Interpreter Richard Sonnenfeldt explains that they brought in Göring to confront Hess but that he too failed to make an impression.
Psychopathologist Prof. Edgar Jones proposes Hess’s behaviour patterns may be his way of escaping reality as he is forced to face the extent of the atrocities and choose between accepting his part of the blame or forsaking his Führer. However, as history Professor Robert Gellatel explains it is difficult to construct a case against Hess as he was imprisoned in England when the worst of the atrocities were carried out so British Prosecutor Mervyn Griffith-Jones must argue a conspiracy charge linking the pre-1939 persecutions to the post-1939 atrocities and a crimes against peace charge proving the flight to Scotland was merely a ruse.

To our medieval forebears the world could appear mysterious, even enchanted. Sightings of green men, dog heads and alien beings were commonplace. The world itself was a book written by God. But as the Middle Ages grew to a close, it became a place to be mastered, even exploited.

David Attenborough reveals the fascinating lives of snakes, the most misunderstood group of reptiles. A CCTV stakeout of wild rattlesnakes hunting shows, for the first time, what sophisticated predators they truly are. Attenborough is also on the receiving end of a spitting cobra's chemical weapons system, while the surprisingly beautiful and tender side of snakes is displayed in the sinuous courtship of kingsnakes, and the water birth of 15 beautiful yellow anaconda babies.