This episode tells the story of how the Emperor Constantine brought Christianity to the western world. In AD 312, Rome was in crisis. The empire had been divided into four parts, each with its own emperor who fought one another. Constantine intervened and united Rome, using military might and a new religion - Christianity.

In AD 410, the Goth hordes sacked the city. This event symbolised Rome's collapse. Within 70 years, the western empire - what we think of as Ancient Rome - was abandoned. But it should never have happened at all.

Julian Richards recalls how, after years of raiding, England's resistance was so weakened that, in the early 11th century, the Vikings were finally able to seize the throne. In other parts of the British Isles however, they gained and maintained power by integration.

In part two, Professor Al-Khalili looks at the 19th century chemists who struggled to impose an order on the apparently random world of the elements. From working out how many there were to discovering their unique relationships with each other, the early scientists' bid to decode the hidden order of the elements was driven by false starts and bitter disputes. But ultimately the quest would lead to one of chemistry's most beautiful intellectual creations - the periodic table.

Francisco de Orellana failed to find El Dorado, but discovered the Amazon. Early in 1541, a rumor swept Quito that beyond the mountains, there lay a land richer than Mexico, or even Peru - a land of gold. The ruler of this land was so rich that he covered himself with gold dust every day and washed it off every evening. He was "the golden man", El Dorado. They had tree goals: to find La Canela, the land of cinnamon: to assess new lands for colonization; and to find El Dorado. On march 1541, They marched eastwards with more that 200 Spanish troops and thousands of native servants.

Cabeza de Vaca was shipwrecked off the coast of Texas in 1528 and lived with Indians for eight years. Upon his return to Spain, he wrote a book based on his experiences. His tale is one of empathy and respect for the Indians. Follow along as Michael Wood traces his journey.