The fourth episode starts off with the two riding through Santa Cruz, Argentina. The plan is to cross over into Chile and then going up into the Andes. Ewan and Charley head through Argentina’s red rock landscape while a member of their team copes with altitude sickness. The duo are well and truly underway and the first signs of all are well is how well the Harleys hold up in challenging conditions. The roads alternate between unforgiving and pleasant and these e-bikes push through effortlessly. As they ride through Chilean Andes, the audience is shown a picturesque view of the beauty of the countryside, an experience which Boorman calls 'magical.'

As the journey continues, there's beauty and danger in equal measure for Charley Boorman and Ewan McGrego. The duo ride their electric Harleys through the exotic and breathtaking Bolivian countryside in a tough ascent. The sixth episode showcases some of the challenges the hosts and the crew face when they scale the terrain. One of the Rivians runs into trouble while sandy roads and a heavy breeze sees Boorman take a tumble. Apart from all the accidents, the chapter also shows some quality work done by UNICEF when it comes to educating and working with the children in Bolivia.
The altitude sickness hits Taylor, their logistics man real bad and McGregor starts feeling it as well. The episode ends with a doctor heading to his hotel room to check up on him.

This remarkable science-history series investigates the blistering pace of human endeavour in space exploration, computing, energy, resources, Earth science and our understanding of the evolution of life itself. Across the last 50 years, humans have set a blistering pace and scientific discovery. We've crossed the boundaries of our solar system, made machines that can learn harnessed the power of the sun and built life from scratch. It's a period like no other in history, where human endeavour is changing everything: this is The Great Acceleration. As we race toward the future, we must examine the journey.
In the first episode, Dr Shalin Naik explores the ambitious space shuttle mission that began in the '70s plus the future colonization of Mars. Over the past 50 years, space has become central to everything, from communications to entertainment to climate modelling. And as private enterprise enters space exploration, our understanding of the universe will only continue to expand. We will know if we can survive on other objects - the moon, maybe Mars, maybe even some of the moons of Jupiter and Saturn. Deep space is the last and infinite frontier. That's what we do as human beings. We explore, we learn, we make discoveries, from the moment we're born to the moment we die.

To help Andrew in his search for love, relationship specialist Jodi Rodgers has come to work with him - on his dating skills. Olivia hasn't given up in her search for love. Today, she's on her way to meet someone new. She's meeting Jackson. Jackson likes origami and the smell of perfume. He hates the sound of nails on a blackboard and people slurping their tea. Jimmy and Sharnae are arriving at the Gold Coast for their first-ever holiday together. And Jimmy has a surprise in store for tomorrow.

As the journey continues, there's beauty and danger in equal measure. Charley and Ewan travel through the extraordinary Bolivian desert, but the sandy roads make all more difficult. The duo ride their electric bikes through the exotic and breathtaking countryside and all the way making a challenging ascent. The riders stay in a hotel made entirely out of salt before heading to La Paz. 'Bolivia' also shows some quality work done by UNICEF when it comes to educating and working with the children. McGregor and Boorman spend time with the kids before resuming their journey and ending with a ferry ride over lake Titicaca.

Ewan and Charley make their way to Peru from Bolivia, and the scenery is just beautiful. Ewan wanted to visit Machu Picchu since he was a kid and decides to show the world the Incan citadel set high in the Andes Mountains. Next up, they make their way to the Cutivireni, a community of Ashaninka people in the Amazon rainforest, with its carbon program to limit the magnitude or rate of global warming and its related effects.