The fourth episode starts off with the two riding through Santa Cruz, Argentina. The plan is to cross over into Chile and then going up into the Andes. Ewan and Charley head through Argentina’s red rock landscape while a member of their team copes with altitude sickness. The duo are well and truly underway and the first signs of all are well is how well the Harleys hold up in challenging conditions. The roads alternate between unforgiving and pleasant and these e-bikes push through effortlessly. As they ride through Chilean Andes, the audience is shown a picturesque view of the beauty of the countryside, an experience which Boorman calls 'magical.'

It's not all about the pouches. These mammalian misfits are full of surprises, from flamboyant kangaroo showdowns to rattling koala mating calls. They might seem a bit bizarre but don't underestimate them. With unexpected superpowers and amazing adaptability, they have conquered a continent.

Mark has never had a girlfriend, but he wants love more than anything. Maddi and Mark are going on their second date at the Australian Museum. Olivia has had 'a bazillion' unrequited loves but is not ready to give up. Maddi dates a new man who impresses her with his musical talent.

Olivia meets someone who seems to truly get her. Andrew has found out about a speed dating event being held in town. He works on his jokes and James Bond impersonations before going to the dinner. Jimmy and Sharnae go on a special holiday together where Jimmy plans a romantic surprise.

To help Andrew in his search for love, relationship specialist Jodi Rodgers has come to work with him - on his dating skills. Olivia hasn't given up in her search for love. Today, she's on her way to meet someone new. She's meeting Jackson. Jackson likes origami and the smell of perfume. He hates the sound of nails on a blackboard and people slurping their tea. Jimmy and Sharnae are arriving at the Gold Coast for their first-ever holiday together. And Jimmy has a surprise in store for tomorrow.

Ewan and Charley make their way to Peru from Bolivia, and the scenery is just beautiful. Ewan wanted to visit Machu Picchu since he was a kid and decides to show the world the Incan citadel set high in the Andes Mountains. Next up, they make their way to the Cutivireni, a community of Ashaninka people in the Amazon rainforest, with its carbon program to limit the magnitude or rate of global warming and its related effects.